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Playersexual "basically means, whatever race or gender the player's character is, the romanceable character finds the player character attractive and can be romanced."
A playersexual character may be bisexual, but this is not necessarily the case. For example, in Dragon Age II, Isabela is confirmed to be bisexual through her in-game behaviour and party banter.  Merrill, another potential LI for a male or female Hawke, does not have an established sexuality outside of her potential romance with the player character.
Discussions about playersexuality can be quite divisive, as seen in a thread on the BioWare forum about the topic: Playerseuxal Characters.
- Brass_Buckles, Playersexual Characters. Posted 17 March 2014. Accessed March 30, 2014)
- Bethany: So you've... been with women. In bed? Isabela: I know. Shocking, isn't it? You see, sweetness, men are only good for one thing. Women are good for six. Bethany: Six? Which six? Hawke: Isabela! Isabela: (Laughs) - Dragon Age II party banter; quote from Dragon Age Wiki